Vertically Self-Oriented, Ultrafast 1D ZnO:Li Nanorods as Scintillators for Thermal Neutron Detection

Detection of special nuclear materials (SNMs) is of vital importance in the prevention of nuclear terrorism and to secure states' national security. Neutron detection is a particularly useful tool to identify SNM, and neutron-sensitive scintillators have many promising properties, such as ease of use, good time resolution, and high detection efficiency. In this work, we develop highly stable, self-oriented, ultrafast 1D ZnO:Li (and codoped with Al, Ga, and In) nanorods (NRs) as thermal neutron-sensitive scintillators. Lithium-6 has high thermal neutron cross section for the (n, alpha) reaction in ZnO:Li scintillators which have a vertical nano array design greatly increasing the effective surface area and scintillation efficiency. Cost-effective low-temperature (95 degrees C) hydrothermal growth is used to obtain highly crystalline ZnO:Li nano scintillators by combining nuclear range data and electron transport mechanisms. Among the studies using low-temperature hydrothermal synthesis and a relatively low annealing temperature (approximate to 350 degrees C) along with optimized NRs (length approximate to 5-8 mu m, mean diameter approximate to 700 nm) for thermal neutron detection, this study reports the shortest scintillation decay time (approximate to 470 ps) so far to the best of our knowledge. This nano array scintillator combines the advantages of a low-cost growth technique with environmentally friendly and widely available materials.

Journal

ACS APPLIED NANO MATERIALS

Year

2025

Volume

8

Issue

43

Pages

20697-20712

eISSN

2574-0970

DOI

10.1021/acsanm.5c03082

WoS UID

WOS:001596001800001