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Article 2023 · 9 citations

Synthesis of Bis-tetraphenylethene as a Novel Turn-On Selective Zinc Sensor

Hussein, Abdullah Saleh, Lafzi, Ferruh, Kilic, Haydar, Bayindir, Sinan

Abstract

The main purpose of this study is the synthesis of novelfluorescent Bis-TPE and the investigation of its widerange of photochemicalbehaviors. For this purpose, initially, Bis-TPE was synthesized.Following this, the interactions of Bis-TPE with a widerange of ions were studied in EtOH using ultraviolet-visible(UV-vis) and fluorescence spectroscopy. As a result of allUV-vis and fluorescence studies, it was determined that Bis-TPE showed turn-on sensor features against Zn2+ ions. Moreover, the limit of detection (LOD) and K (a) values of Bis-TPE/Zn2+ were calculated as0.97 & mu;M (970 nM) and 3.76 x 10(5) M-1, respectively. Moreover, all reversal studies resulted in switchableon/off variation of the alternative addition of ZnCl2 and[Bu4N]OH to Bis-TPE. This result also impliesthat the probe Bis-TPE also exhibits specific OH- sensor properties in the presence of zinc.

Keywords
AGGREGATION-INDUCED EMISSION OFF FLUORESCENT-PROBE HYDROGEN-SULFIDE SCHIFF-BASE ZN2+ RECOGNITION HG2+ ION CHEMOSENSOR ESIPT
WoS Categories
Chemistry, Multidisciplinary
Sustainable Development Goals
Citation
Journal
ACS OMEGA
Year
2023
Volume
8
Issue
28
Pages
25432-25440
ISSN
2470-1343
DOI
10.1021/acsomega.3c02955
WoS UID
WOS:001021452100001
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