Article 2022 · 26 citations

Selectfluor and TBAX (Cl, Br) Mediated Oxidative Chlorination and Bromination of Olefins

Dagalan, Ziya, Kocak, Ramazan, Dastan, Arif, Nisanci, Bilal

Abstract

Herein, we report the first metal-free and molecular halogen reagent-free dihomohalogenation methodology by using Selectfluor as an oxidant and tetrabutylammonium bromide/ chloride salts as a halogen source. This effective strategy provides various fluorine-free halogenated products easily in quantitative yields from alkenes, alkynes, and natural products.

Keywords

EFFICIENT CATALYTIC-SYSTEM NHC-AUCL/SELECTFLUOR

WoS Categories

Chemistry, Organic

Citation

Journal: ORGANIC LETTERS
Year: 2022
Volume: 24
Issue: 45
Pages: 8261-8264
ISSN: 1523-7060
eISSN: 1523-7052
DOI: 10.1021/acs.orglett.2c02627
WoS UID: WOS:000861210500001

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