Thermally Processed Quantum-Dot Polypropylene Composite Color Converter Film for Displays
Fang, Fan, Wen, Zuoliang, Chen, Wei, Wang, Zhaojin, Sun, Jiayun, Liu, Haochen, Tang, Haodong, Hao, Junjie, Liu, Pai, Xu, Bing, Zhang, Zhikuan, Wang, Kai, Teo, Kie Leong, Ertugrul, Mehmet, Lei, Wei, Sun, Xiao Wei
Quantum dots (QDs) have attracted much attention as one of the most promising candidates for next-generation display materials. However, stability is still a big challenge for QDs. Herein, we encapsulated QDs in a thermoplastic polypropylene (PP) matrix by thermal processing technology to prepare a stabler color conversion film for the first time. Thermal processing technology expands the packaging materials of QDs from traditional soluble polymers to thermoplastic polymers such as PP with easy processing and a low cost. We showed that the QDs in the PP film exhibited longerlasting stability than the traditional PMMA film. After 216 h of blue light accelerated aging test, the QDs maintained more than 90% of the initial performance in the PP film but dropped to less than 25% in the PMMA film. Moreover, the reasons for the improved stability have been further discussed. It was found that the PP-H film not only possessed better barriers to moisture and oxygen, but the absence of ester groups also led to a milder environment around the QDs. The results show that ester groups have stronger electronegativity and easily cause the ligands on the surface of QDs to fall off, which lead to performance degradation.
- Journal
- ACS APPLIED MATERIALS & INTERFACES
- Year
- 2022
- Volume
- 14
- Issue
- 27
- Pages
- 31160-31169
- ISSN
- 1944-8244
- eISSN
- 1944-8252
- DOI
- 10.1021/acsami.2c08669
- WoS UID
- WOS:000827090700001