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Article 2025 · 2 atıf

Enhanced tribocorrosion and corrosion resistance of R4 grade mooring chain steel through hybrid ceramic coatings

Comakli, Onur, Meletlioglu, Emrah

Özet

This study investigates the microstructure, corrosion resistance, and tribocorrosion properties of a hybrid ceramic layer applied to R4-grade mooring chain steel. The coatings were produced using a two-step process: boriding followed by applying a titanium carbon-nitride (TiCN) layer via the Physical Vapor Deposition (PVD) process. X-ray diffraction (XRD) tests verified the creation of FeB, Fe2B, and TiCN phases. The borided layer provided a gradient-hardened structure, improving load-bearing capacity, while the TiCN film enhanced surface hardness. The electrochemical tests demonstrated that the hybrid ceramic coating considerably enhanced corrosion resistance compared to untreated and borided samples. Tribocorrosion tests revealed that the hybrid ceramic layer exhibited superior wear resistance, with a lower coefficient of friction and reduced wear rates. These findings indicate that the hybrid ceramic coating system can significantly enhance electrochemical and tribocorrosion resistance in seawater, extending the service life of R4 steel.

Anahtar Kelimeler
R4 steel hybrid ceramic coating Boriding TiCN Tribocorrosion Corrosion resistance WEAR PROPERTIES TICN COATINGS MECHANICAL-PROPERTIES SURFACE-TREATMENT FILMS BEHAVIOR IRON TIN STRENGTH GROWTH
WoS Kategorileri
Materials Science, Ceramics
Künye
Dergi
CERAMICS INTERNATIONAL
Yıl
2025
Cilt
51
Sayı
12
Sayfa
15706-15716
ISSN
0272-8842
eISSN
1873-3956
DOI
10.1016/j.ceramint.2025.01.407
WoS UID
WOS:001481469800001
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