Article 2021 · 36 atıf

Carbon aerogel and their polypyrrole composites used as capacitive materials

Samanci, Meryem, Das, Elif, Bayrakceken Yurtcan, Ayse

Özet

Supercapacitors are the electrochemical capacitors with high energy density. In this study, first, carbon aerogels (CAs) having different structural properties (surface areas and pore diameters) were synthesized. Their polypyrrole (PPy) composites on these CAs were synthesized via oxidative polymerization. The change in the capacitive properties depending on both different CA structural properties and PPy addition was determined. The materials were characterized by Fourier Transform Infrared Spectrocope (FTIR), X-ray diffraction (XRD), nitrogen adsorption/desorption isotherms with Brunauer, Emmett and Teller (BET) method, scanning electron microscope (SEM), transmission Electron Microscope (TEM), elemental analysis and thermal gravimetric analysis (TGA) methods. Specific capacitances of the nanocomposites were determined by cyclic voltammetry (CV) method for fresh electrode and the aged electrode after 1000 cycles. It was observed that the specific capacitance of the composite obtained with the addition of PPy to the first type of carbon aerogel (CA1) material varies significantly and increased from 147 F g(-1)(CA1) to 231 F g(-1)(CA1/PPy).

Anahtar Kelimeler

carbon aerogel polypyrrole nanocomposite supercapacitor supercritical carbon dioxide ELECTROCHEMICAL PROPERTIES ELECTRODE MATERIAL MESOPOROUS CARBON CATALYST SUPPORT POROUS CARBON GRAPHENE SUPERCAPACITORS PERFORMANCE NANOTUBE

WoS Kategorileri

Energy & Fuels Nuclear Science & Technology

Künye

Dergi: INTERNATIONAL JOURNAL OF ENERGY RESEARCH
Yıl: 2021
Cilt: 45
Sayı: 2
Sayfa: 1729-1747
ISSN: 0363-907X
eISSN: 1099-114X
DOI: 10.1002/er.5841
WoS UID: WOS:000565873000001

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